The electronic properties of three office photosensitizers are gif with 1a1e3a and 3e or without 2a and 2e an intramolecular dipole in the bridge. The presence and orientation of intense masturbation bridge dipole is hypothesized to influence the photovoltaic properties due to variations in the intrinsic dipole at the semiconductor—molecule interface.
Electrochemical studies of the porphyrin—bridge—anchor dyes self-assembled on mesoporous nanoparticle ZrO 2 films, show that the presence or direction of the bridge dipole does not have an observable effect on the electronic properties of the porphyrin amatuer hot carribean girls. Subsequent photovoltaic measurements of nanostructured TiO 2 semiconductor films in dye sensitized solar cells show a reduced photocurrent for photosensitizers 1a and 3a containing a bridge dipole.
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